标题:Treatment of Organic Pollutants Using Electro-Fenton and Electro-Fenton-Like Process in Aqueous Solution作者:Lin Heng; Zhang Hui
来源出版物:PROGRESS IN CHEMISTRY 卷:27 期:8页:1123-1132 DOI:10.7536/PC141233 出版年:AUG 2015
摘要:Conventional Fenton process is one of the promising advanced oxidation technologies (AOTs) for the treatment of organic pollutants in water. In Fenton process, hydroxyl radical ((OH)-O-center dot), a kind of strong oxidant, is formed through Fenton's reaction and then degrades organic pollutants. Similar to conventional Fenton process, transition metal ions (Fe2+, Co2+, Ag+, etc.) can also activate persulfate (PS) and generate sulfate radicals (SO4 center dot-, SR). Sulfate radical is a powerful oxidant and can oxidize most of organic pollutants. This process is named as "Fenton-like process". There are some disadvantages existed in conventional Fenton and Fenton-like process. For example, a high concentration of Fe2+ is required and a large amount of iron sludge is generated. In order to solve these problems, electro-Fenton and SR-based electro-Fenton-like processes are proposed. Fe2+ can be regenerated via cathodic reduction in electro-Fenton and electro-Fenton-like processes. Therefore, the Fe2+ concentration used in these processes is much lower than that in Fenton and Fenton-like processes. This paper provides an overview of mechanism and research progress of electro-Fenton and SR-based electro-Fenton-like processes. The types and improvements for electro-Fenton and electro-Fenton-like processes are summarized. Moreover, the prospects of the research areas meriting further investigation and developed trends are pointed out.
入藏号:WOS:000359884000015
文献类型:Review
语种:Chinese
作者关键词:electro-Fenton, electro-Fenton-like, hydroxyl radicals, sulfate radicals, organic pollutants
扩展关键词:ACID ORANGE 7; ENHANCED HETEROGENEOUS ACTIVATION; ADVANCED OXIDATION PROCESSES; PHOTO-ASSISTED DEGRADATION; SITU CHEMICAL OXIDATION; LANDFILL LEACHATE; ELECTRO/FE2+/PEROXYDISULFATE PROCESS; 2,4,5-TRICHLOROPHENOXYACETIC ACID; WATER DECONTAMINATION; PERSULFATE OXIDATION
通讯作者地址:Zhang Hui; Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China.
电子邮件地址:eeng@whu.edu.cn
地址: [Lin Heng; Zhang Hui] Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China.
研究方向:Chemistry
ISSN:1005-281X
影响因子(2014):0.687