标题:Verification and implications of the dissolution-electrodeposition process during the electro-reduction of solid silica in molten CaCl2
作者:Xiao, W(Xiao, Wei); Wang, X(Wang, Xin); Yin, HY(Yin, Huayi); Zhu, H(Zhu, Hua); Mao, XH(Mao, Xuhui); Wang, DH(Wang, Dihua)
来源出版物:RSC ADVANCES 卷:2 期:19 页:7588-7593 出版年:2012
摘要:With the verification of the existence of the dissolution-electrodeposition mechanism during the electro-reduction of solid silica in molten CaCl2, the present study not only provides direct scientific support for the controllable electrolytic extraction of nanostructured silicon in molten salts but it also opens an avenue to a continuous silicon extraction process via the electro-deposition of dissolved silicates in molten CaCl2. In addition, the present study increases the general understanding of the versatile material extraction route via the electro-deoxidization process of solid oxides in molten salts, which also provokes reconsiderations on the electrochemistry of insulating compounds
扩展关键词:3-PHASE INTERLINES; ELECTROCHEMICAL PREPARATION; INSULATOR COMPOUNDS; CALCIUM-CHLORIDE; SIO2 PELLETS; NANOWIRES; ELECTROREDUCTION; DIOXIDE; MECHANISM; TITANIUM
通讯作者地址:Xiao, W (通讯作者),Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Peoples R China
[Xiao, Wei; Wang, Xin; Yin, Huayi; Zhu, Hua; Mao, Xuhui; Wang, Dihua]Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Peoples R China
[Wang, Dihua] Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect,Shenyang 110016, Peoples R China